WebHere, we report measurement of the covalency of a terminal uranium(VI)-nitride by 15N nuclear magnetic resonance spectroscopy, and find an … WebIn the complexes, the overall bond strength of salen exceeds pyren, except for the Pa case. This can be explained by a greater degree of polarizability for the Pa 5 f 1 state. More information can be found in the Full Paper by J. März …
X-ray absorption spectra of f-element complexes: insight from ...
WebFront Cover: How 5 f Electron Polarisability Drives Covalency and Selectivity in Actinide N‐Donor Complexes (Chem. Eur. J. 72/2024) Luisa Köhler , Michael Patzschke , Moritz Schmidt , Thorsten Stumpf , Juliane März WebOct 21, 2024 · QTAIM has been successfully used to characterise the bonding interactions in many f-element complexes. 21,23,25–34 One of the earliest applications of QTAIM analysis in f-element chemistry was conducted by Kaltsoyannis and co-workers. 25,26 In these contributions, the covalency in AnCp 4 and AnCp 3 complexes (An = Th-Cm) … installer docker compose ubuntu
Bonding of isovalent homologous actinide and …
WebSep 1, 2024 · @article{osti_1656900, title = {Actinide N-Donor Thermodynamics: Expanding the f-element Covalency Dialogue. Final report}, author = {Shafer, Jenifer}, abstractNote = {Resolving the chemistry and physics of f-electrons is one of the grand challenges of science for energy technology. A central component of this challenge is … WebApr 13, 2024 · An increase in the valence state of the 3d element correlates with a shift of the pre-edge to lower energy and an enhancement of the spectral intensity due to the strong covalence 21,34,35. WebThe geometric and electronic structures of the title complexes have been studied using scalar relativistic, gradient-corrected density functional theory. Extension of our previous … installer domoticz raspberry