Optical basicity definition

WebFeb 13, 2024 · The concept of “basicity ” has been central to our understanding of slag chemistry for many decades. Traditionally, basicity has been connected to the level of … WebThe concept of optical basicity (Λ) is particularly suited to binary oxides and oxidic network materials such as silicates to characterize the acid–base nature of glasses and melts and to account for the complexation of metal cations by a variety of anionic frameworks.

Polarisability and polarising power of rare earth ions in glass: an ...

WebJul 1, 2001 · The basicity (i.e. %CaO/%SiO2) or J o u r n a l P r e -p r o o f basicity indices (weight ratio of basic oxides to acid oxides) are often used to evaluate the chemical … WebThe optical basicity of complex nitrides can therefore be calculated by the same method established for oxides using the equivalent fractions and the basicity of the constituent nitrides. The relationship between nitride polarizability α N and basicity Λ(nitride) was found to be linear, with Λ(nitride) = 0.39α N − 0.14 where α N is given ... how much pf contribution can be increased https://voicecoach4u.com

Anion polarizabilities in oxynitride glasses. Establishing a …

WebSlag Basicity is a measure of the acidic-basic character of the oxides, widely used by the glass scientists, slag metallurgists and some geologists as well. You will get the details … WebNov 30, 2024 · modifier. The molar polarizability, αm, oxide ion polarizability, αo2-and optical basicity, Λ of the glasses are calculated by Lorentz-Lorenz equation. The glasses were found to possess αm values 3, and αo2-values between 3.303 to 4.772. Meanwhile, optical basicity increases from 0.115 to 0.893. Keywords: barium oxide, refractive index ... http://www.ecm.okayama-u.ac.jp/ceramics/Research/Papers/2011/Nanba_JCSJ_119(2011)720.pdf how do i write a monologue

Optical Basicity and Refractivity of Germanate Glasses

Category:Optical Basicity and Refractivity of Germanate Glasses

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Optical basicity definition

Correlation between optical basicity, electronegativity and electroni…

WebJul 27, 2011 · Basicity is expressed using the Smith {alpha} parameter scale. A linear relation was found between the oxide electronegativity and the Smith {alpha} parameter, … WebAug 1, 1993 · 4) Optical basicity is a concept arising from a consideration of the ionic/covalent nature of bonding between a Lewis acid and base and is quantitatively …

Optical basicity definition

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WebIt is shown that optical basicity avoids the confusion that can arise from the use of empirical basicity ratios, particularly with regard to the effect of magnesia, and in addition,... WebThe optical basicity of complex nitrides can therefore be calculated by the same method established for oxides using the equivalent fractions and the basicity of the constituent …

http://www.ecm.okayama-u.ac.jp/ceramics/Research/Papers/2011/Nanba_JCSJ_119(2011)720.pdf WebFeb 1, 2024 · The concept of optical basicity (Λ) is particularly suited to binary oxides and oxidic network materials such as silicates to characterize the acid–base nature of glasses and melts and to account for the complexation of metal cations by a variety of anionic …

WebAug 13, 2002 · The acid−base properties of germanate glasses cannot presently be compared quantitatively with those of silicate, borate, and several other glasses because the optical basicity of the parent oxide, Λ(GeO2), has not yet been unequivocally established. The usual method of measuring optical basicity, relying on probe ions such as Tl+ or … WebPolarisability and polarising power of rare earth ions in glass: an optical basicity assessment — The University of Aberdeen Research Portal Polarisability and polarising power of rare earth ions in glass: an optical basicity assessment John A Duffy Chemistry Research output: Contribution to journal › Article › peer-review 41 Citations (Scopus)

WebAug 17, 1998 · The optical basicity Λ of the oxides has been estimated on the basis of average electronic oxide polarizability calculated from the refractive index Λ(n 0) and the energy gap Λ(E g). A good agreement has been observed between the optical basicity data obtained using independent initial quantities. how do i write a manuscriptWebFeb 25, 2002 · The optical basicity for La 2 O 3 oxide is found to be 1.07, being much larger compared with typical glass-forming oxides such as B 2 O 3 (0.42) and SiO 2 (0.48) but … how much pf is contributed by employerWebBasicity (in metallurgy), the ratio (in percent by weight) of basic and acidic oxides in iron ore materials (iron ore, sinter, and pellets), and also in blast-furnace and steel-smelting slag. Basicity defines the chemical composition and metallurgical properties of such materials. how much ph does lemon juice haveWebOct 10, 2024 · Optical basicity is identified as the average electron donor power of a fluorinated or oxidic compound ( Herrmann et al., 2015 ). For a glass system consisting of … how do i write a permission letter to travelWebOptical basicity: a scale of acidity/basicity of solids and its application to oxidation catalysis. Elisabeth Bordes-Richard, Pierre Courtine To cite this version: Elisabeth Bordes … how do i write a playWebEllipsometry is an optical technique that measures changes in polarization (phase, Δ, and amplitude, Ψ) of monochromatic light reflecting from matter, and these standard ellipsometric parameters Ψ and Δ are related to the complex ratio of reflection coefficient for light polarized parallel p and perpendicular s to the plane of incidence. 2.3.3. how much ph does milk haveWebJun 25, 2024 · So, lanthanum is accountable for the increase of non-bridging oxygen due to this shift is obtained. So, the optical bandgap of these glasses has been decreased as well as the refractive index. Polarizability and basicity of the prepared glasses according to the refractive index and optical bandgap have been investigated. how much ph does distilled water have